Publication:
Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

No Thumbnail Available
Date
2012-05-01T00:00:00Z
Authors
ERTURK, Erkan
Tezeren, Mustafa Ali
TİLKİ, Tahir
ERDOGAN, Tuba
Goren, AHMET CEYHAN
Journal Title
Journal ISSN
Volume Title
Publisher
Research Projects
Sustainable Development Goals
Organizational Units
Journal Issue
Abstract
The readily available mixed-valent iron trifluoroacetate complex [Fe2IIIFeII(mu 3-O)(O2CCF3)6(H2O)3] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.00.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end-group analysis by 19F NMR spectroscopy, a Lewis acid (LA?) catalyzed anionic reaction mechanism is proposed. Copyright (c) 2012 Society of Chemical Industry
Description
Keywords
Citation
ERTURK E., Tezeren M. A. , TİLKİ T., ERDOGAN T., Goren A. C. , -Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]-, POLYMER INTERNATIONAL, cilt.61, ss.795-799, 2012