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Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

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dc.contributor.authorERTURK, Erkan
dc.contributor.authorTezeren, Mustafa Ali
dc.contributor.authorTİLKİ, Tahir
dc.contributor.authorERDOGAN, Tuba
dc.contributor.authorGoren, AHMET CEYHAN
dc.contributor.institutionauthorGÖREN, AHMET CEYHAN
dc.date.accessioned2020-10-29T21:34:43Z
dc.date.available2020-10-29T21:34:43Z
dc.date.issued2012-05-01T00:00:00Z
dc.description.abstractThe readily available mixed-valent iron trifluoroacetate complex [Fe2IIIFeII(mu 3-O)(O2CCF3)6(H2O)3] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.00.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end-group analysis by 19F NMR spectroscopy, a Lewis acid (LA?) catalyzed anionic reaction mechanism is proposed. Copyright (c) 2012 Society of Chemical Industry
dc.identifier.citationERTURK E., Tezeren M. A. , TİLKİ T., ERDOGAN T., Goren A. C. , -Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]-, POLYMER INTERNATIONAL, cilt.61, ss.795-799, 2012
dc.identifier.doi10.1002/pi.4141
dc.identifier.scopus84859464631
dc.identifier.urihttp://hdl.handle.net/20.500.12645/26331
dc.identifier.wosWOS:000302541200018
dc.titlePolymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]
dc.typeArticle
dspace.entity.typePublication
local.avesis.id910a1f8c-ba8a-4548-ac1b-6b39c105b9e6
local.indexed.atWOS
local.indexed.atScopus
local.publication.isinternational1
relation.isAuthorOfPublication07fcea81-8515-4cd4-86f2-047fe6b2df71
relation.isAuthorOfPublication.latestForDiscovery07fcea81-8515-4cd4-86f2-047fe6b2df71

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