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Intramolecular Cross-linking of Polymers Using Difunctional Acetylenes via Click Chemistry

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2011-01-01T00:00:00Z
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Cengiz, Halime
Aydogan, BİNNUR
Ates, Sahin
Acikalin, Engin
Yağcı, Yusuf
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Abstract
An efficient approach was described for the intramolecular cross-linking of azide-functionalized poly(styrene-co-chloromethyl styrene) co-polymers (PS-N-3) via click chemistry at room temperature. Reaction of PS-N-3 with the appropriate diacetylene functional compounds such as 1,4-diethynylbenzene (DEB) and 1,10-dipropargyloxy decane (DPD) in ultra-dilute solutions led to unimolecular particle-like structures. The resulting polymers were characterized in detail by H-1-NMR, FT-IR, GPC and DSC measurements. (C) Koninklijke Brill NV, Leiden, 2011
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Cengiz H., Aydogan B., Ates S., Acikalin E., Yağcı Y., -Intramolecular Cross-linking of Polymers Using Difunctional Acetylenes via Click Chemistry-, DESIGNED MONOMERS AND POLYMERS, cilt.14, ss.69-78, 2011
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http://hdl.handle.net/20.500.12645/25906
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