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Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications

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dc.contributor.authorAtes, Sahin
dc.contributor.authorAydogan, BİNNUR
dc.contributor.authorTORUN, Lokman
dc.contributor.authorYağcı, Yusuf
dc.contributor.institutionauthorTEMEL, BİNNUR
dc.date.accessioned2020-10-29T23:04:48Z
dc.date.available2020-10-29T23:04:48Z
dc.date.issued2010-02-15T00:00:00Z
dc.description.abstractA novel triptycene type diacrylate cross-linker, triptycene hydroquinone diacrylate (THDA) was synthesized from the reaction of triptycene hydroquinone with acryloyl chloride and characterized. The photocuring behaviour and the reaction kinetics of the synthesized cross-linker were investigated by means of photo-differential scanning calorimetry (photo-DSC) experiments. Formulations containing monofunctional (meth)acrylate monomers, namely glycidyl methacrylate (GMA), 2-hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (HEMA), and 2-ethylhexyl methacrylate (EHMA), crosslinker, THDA and 2,2-dimethoxy-2-phenylacetophenone (DMPA) as a photoinitiator were irradiated. A conventional cross-linker without triptycene unit Such as hydroquinone diacrylate (HDA) was used under the same conditions for comparison. The effects of the Structure of the monofunctional monomer and triptycene moiety on the photopolymerization kinetics were evaluated and discussed. (C) 2010 Elsevier Ltd. All rights reserved.
dc.identifier.citationAtes S., Aydogan B., TORUN L., Yağcı Y., -Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications-, POLYMER, cilt.51, ss.825-831, 2010
dc.identifier.doi10.1016/j.polymer.2010.01.005
dc.identifier.scopus75749115928
dc.identifier.urihttp://hdl.handle.net/20.500.12645/26884
dc.identifier.wosWOS:000274679700001
dc.titleSynthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications
dc.typeArticle
dspace.entity.typePublication
local.avesis.idce9b5a77-5e38-4eba-8402-6d2c97eb4697
local.publication.isinternational1
relation.isAuthorOfPublicationd73c61cc-93fa-4fce-a294-f68e807cd50a
relation.isAuthorOfPublication.latestForDiscoveryd73c61cc-93fa-4fce-a294-f68e807cd50a
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