Publication:
Graft Copolymers via ROMP and Diels-Alder Click Reaction Strategy

dc.contributor.authorDurmaz, Hakan
dc.contributor.authorDag, Aydan
dc.contributor.authorCerit, Nese
dc.contributor.authorSirkecioğlu, Okan
dc.contributor.authorHızal, Gürkan
dc.contributor.authorTunca, Ümit
dc.contributor.institutionauthorDAĞ, AYDAN
dc.date.accessioned2020-10-29T21:56:10Z
dc.date.available2020-10-29T21:56:10Z
dc.date.issued2010-12-15T00:00:00Z
dc.description.abstractAnthracene functionalized oxanorbornene monomer and oxanorbornenyl polystyrene (PS) with omega anthracene end functionalized macromonomer were first polymerized via ring opening metathesis polymerization using the first generation Grubbs catalyst in dichloromethane at room temperature and then clicked with maleimide end functionalized polymers poly(ethylene glycol) (PEG) MI poly(methyl methacrylate) (PMMA) MI and poly(tert butyl acrylate) (PtBA) MI in a Diels-Alder reaction in toluene at 120 degrees C to create corresponding graft copolymers poly(oxanorbornene) g PEG poly(oxanorbor nene) g PMMA and graft block copolymers poly(oxanorbor nene) g (PS b-PEG) poly(oxanorbornene) g (PS b-PMMA) and poly(oxanorbornene) g (PS b-PtBA) respectively Diels-Alder click reaction efficiency for graft copolymerization was moni tored by UV-vis spectroscopy The dn/dc values of graft copolymers and graft block copolymers were experimentally obtained using a triple detection gel permeation chromatogra phy and subsequently introduced to the software so as to give molecular weights intrinsic viscosity ([eta]) and hydrodynamic radius (R-h) values (C) 2010 Wiley Periodicals Inc J Polym Sci Part A Polym Chem 48 5982-5991 2010
dc.identifier.citationDurmaz H., Dag A., Cerit N., Sirkecioğlu O., Hızal G., Tunca Ü., -Graft Copolymers via ROMP and Diels-Alder Click Reaction Strategy-, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.48, ss.5982-5991, 2010
dc.identifier.doi10.1002/pola.24418
dc.identifier.scopus78649595369
dc.identifier.urihttp://hdl.handle.net/20.500.12645/26473
dc.identifier.wosWOS:000285485700041
dc.titleGraft Copolymers via ROMP and Diels-Alder Click Reaction Strategy
dc.typeArticle
dspace.entity.typePublication
local.avesis.ida3af6113-2eee-414d-b610-4b079bdd8c72
local.publication.isinternational1
relation.isAuthorOfPublication5053fdfd-57cd-423a-9076-db4bab8cbe3d
relation.isAuthorOfPublication.latestForDiscovery5053fdfd-57cd-423a-9076-db4bab8cbe3d
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