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Microgels from microfluidic templating and photoinduced crosslinking of cinnamylidene acetic acid modified precursors

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dc.contributor.authorTuncaboylu, DENİZ CEYLAN
dc.contributor.authorWISCHKE, C.
dc.contributor.authorSTOERMANN, F.
dc.contributor.authorLENDLEIN, A.
dc.contributor.institutionauthorTUNCABOYLU, DENIZ CEYLAN
dc.date.accessioned2019-10-05T21:43:29Z
dc.date.available2019-10-05T21:43:29Z
dc.date.issued2017-03-01
dc.description.abstractSo far, a number of approaches to synthesize microgel networks have been followed, while only in few cases a detailed control of the network architecture has been possible. Here, the photoinduced [2 + 2] cycloaddition reaction of cinnamylidene acetic acid (CAA) moieties coupled to four-arm star shaped oligo (ethylene glycol) (OEG) precursors was explored for the creation of microgels with defined polymer network structures. Based on a rational solvent selection and precursor dispersion in glass-capillary microfluidics, microgels could be successfully prepared by the proposed synthesis approach. Model reactions confirmed a quantitative network formation. Therefore, compared to common radical polymerization for microgel crosslinking, CAA-dimerization may be an alternative approach particularly when well defined network structures are desired. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier
dc.identifier.citationTuncaboylu D. C. , WISCHKE C., STOERMANN F., LENDLEIN A., -Microgels from microfluidic templating and photoinduced crosslinking of cinnamylidene acetic acid modified precursors-, REACTIVE & FUNCTIONAL POLYMERS, cilt.112, ss.68-73, 2017
dc.identifier.urihttps://hdl.handle.net/20.500.12645/8061
dc.language.isoen
dc.titleMicrogels from microfluidic templating and photoinduced crosslinking of cinnamylidene acetic acid modified precursors
dc.typeArticle
dspace.entity.typePublication
local.article.journalnameTURK OFTALMOLOJI GAZETESI
local.avesis.idc8607170-d459-458d-b092-c4fadc4621b3
local.avesis.response7937
relation.isAuthorOfPublicationac53edd0-862b-4855-8c83-91c45c3cfd61
relation.isAuthorOfPublication.latestForDiscoveryac53edd0-862b-4855-8c83-91c45c3cfd61
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